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Removal of Cu2+ from aqueous water by adsorption onto the efficient and recyclable durian Shell-derived activated carbon / Long Giang Bach, Dai-Viet N. Vo, Nguyen Duy Trinh, Van Thi Thanh Ho, Van Thuan Tran // Applied Mechanics and Materials. - . - Vol. 876 (2018), P.46-51. - ISSN:

Switzerland : Trans Tech Publications, 2018
6 p.
Ký hiệu phân loại (DDC): 542
We investigated the use of durian shell-derived activated carbon (DSAC) for the removal of Cu2+. To determine the optimal condition for Cu2+ removal, the response surface methodology (RSM) was used to establish a second-order polynomial model with variables such as Cu2+ concentration (Ci), adsorbent dosage (dDSAC) and pH. With R2 = 0.9847 and P-value < 0.0001, the model was proved to be statistically significant. The RSM based confirmation test revealed that the removal of Cu2+ was maximum (99.6%) at optimal conditions: Ci = 61.6 mg/L, dDSAC = 5.0 g/L and pH = 5.2. Based on calculated R2, data fitness for adsorption isotherms were positioned as follows: Langmuir > Tempkin > Freundlich. In other words, monolayer adsorption was the most favorable behavior with maximum capacity of 76.92 mg/g from Langmuir model. Interestingly, DSAC was reused at least five times without a considerable decrease of Cu2+ removal efficiency. Therefore, durian shell can be used as a highly effective, reusable and promising raw material to fabricate the activated carbon.
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The comparison of surface modification methods of the heavy metals adsorption of activated carbon from rice husk / Hoa Thai Ma, Van Thi Thanh, Nguyen Bao Pham, Giang Long Bach, Tuan Dinh Phan // Applied Mechanics and Materials. - . - Vol. 876 (2018), P.91-96. - ISSN:

Switzerland : Trans Tech Publications, 2018
6 p.
Ký hiệu phân loại (DDC): 542
Surface modification of activated carbon (AC) could be done through different methods in order to modify their specific physical and chemical properties to facilitate metals removal from wastewater. Three methods were used to modify the rice husk AC (RHAC) including the use of (1) HNO3, (2) dithizone and (3) the combination of HNO3 with dithizone. These modification agents were increased its affinity towards the desired pollutant. The modification methods demonstrated the effective process for the metal ions adsorption capability and the removal of them from water. For Ni2+ and Cd2+ adsorption, RHAC was modified by HNO3 giving the best adsorption capacity in comparison with using dithizone or the combination of HNO3 with dithizone. That adsorption was reached 17.23 mg/g for Ni2+ and 29.61 mg/g for Cd2+. Additionally, the surface area, which was characterized by BET (Brunauer–Emmett–Teller) of RHAC, was 710.8 m2/g and DA micropore volume was 0.447 (cm3/g). Especially, the only modified RHACs had the peak of N-H functional group by using Fourier transform infrared spectrum (FTIR). Besides, the only RHAC modification by HNO3 had peak of C=O. That significantly contributed to increase the metal ions adsorption capacity of RHAC.
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