Dòng Nội dung
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Preparation and characterization of advanced PtRu/Ti0.7Mo0.7O2 catalysts for direct methanol fuel cells / Van Thi Thanh Ho, Long Giang Bach, Dai-Viet N. Vo // Applied Mechanics and Materials. - . - Vol. 876 (2018), P.57-63. - ISSN:

Switzerland : Trans Tech Publications, 2018
7 p.
Ký hiệu phân loại (DDC): 542
We report the new strategy by investigating the novel Ti0.7Mo0.3O2 material can just as easily be used as a conductive support for PtRu for DMFCs to prevent not only the carbon corrosion but also improved activity of catalyst due to some functional advantages of novel Ti0.7Mo0.3O2 support. The Ti0.7Mo0.3O2 nanoparticle have good crystallinity with well-defined fringes corresponding to the 3.45 Å spacing value of the {101} plane of anatase TiO2, which were good according to the XRD pattern. The BET surface area measurements showed that the Ti0.7Mo0.3O2 possessed 125 m2 g-1 Fig. 3 shows the TEM measurement of Ti0.7Mo0.3O2 nanoparticle and Pt/Ti0.7Mo0.3O2, it can be observed that spherical PtRu alloy particles with an average particle size of 2-4 nm were uniformly anchored on the surface of Ti0.7Mo0.3O2 support. More importantly, we found that there has a strong metal support interaction (SMSI) between the PtRu noble metal and the Ti0.7Mo0.3O2 support material - resulting in facile electron donation from the Ti0.7Mo0.3O2 support to PtRu metal with an ultimate drastic decrease in the d-band vacancy of Pt. Thus, the unique structural features of the Ti0.7Mo0.3O2 support and the PtRu/Ti0.7Mo0.3O2 catalyst appear to provide a suitable combination favoring that promise for the high performance of methanol oxidation, CO-tolerance in DMFCs.
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Removal of Cu2+ from aqueous water by adsorption onto the efficient and recyclable durian Shell-derived activated carbon / Long Giang Bach, Dai-Viet N. Vo, Nguyen Duy Trinh, Van Thi Thanh Ho, Van Thuan Tran // Applied Mechanics and Materials. - . - Vol. 876 (2018), P.46-51. - ISSN:

Switzerland : Trans Tech Publications, 2018
6 p.
Ký hiệu phân loại (DDC): 542
We investigated the use of durian shell-derived activated carbon (DSAC) for the removal of Cu2+. To determine the optimal condition for Cu2+ removal, the response surface methodology (RSM) was used to establish a second-order polynomial model with variables such as Cu2+ concentration (Ci), adsorbent dosage (dDSAC) and pH. With R2 = 0.9847 and P-value < 0.0001, the model was proved to be statistically significant. The RSM based confirmation test revealed that the removal of Cu2+ was maximum (99.6%) at optimal conditions: Ci = 61.6 mg/L, dDSAC = 5.0 g/L and pH = 5.2. Based on calculated R2, data fitness for adsorption isotherms were positioned as follows: Langmuir > Tempkin > Freundlich. In other words, monolayer adsorption was the most favorable behavior with maximum capacity of 76.92 mg/g from Langmuir model. Interestingly, DSAC was reused at least five times without a considerable decrease of Cu2+ removal efficiency. Therefore, durian shell can be used as a highly effective, reusable and promising raw material to fabricate the activated carbon.
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Synthesis the new nanostructure Ti0.7Ir0.3O2 via low temperature hydrothermal process / Tai Thien Huynh, At Van Nguyen, Hau Quoc Pham, Long Giang Bach, Van Thi Thanh Ho // Applied Mechanics and Materials. - . - Vol. 876 (2018), P.64-70. - ISSN:

Switzerland : Trans Tech Publications, 2018
7 p.
Ký hiệu phân loại (DDC): 542
Noncarbon materials were recognized as the catalyst support to increase the durability of Proton Exchange Membrane Fuel Cells (PEMFC). One of the most noncarbon materials studied to be an emerging candidate for Pt nanoparticles (Pt NPs) support on the cathode side of PEMFC was M doped-TiO2 due to the highly stable structure of TiO2 and the good conductivity of M-doped TiO2. In this paper, the novel nanostructure Ti0.7Ir0.3O2 was prepared for the first time via low temperature hydrothermal process. The synthesis process for the new nanostructure Ti0.7Ir0.3O2 was studied in detail in this work. The impact of hydrothermal temperature as well as the reaction time on the dominant phase formation is extensively investigated in this work. We found that the Ti0.7Ir0.3O2 nanoparticles exist in both rutile and anatase phase. We found that the Ti0.7Ir0.3O2 nanoparticles with an irregular spherical shape with particle size of approximately 20-30nm with high crystallinity. In addition, we also found that the optimal condition to synthesize the Ti0.7Ir0.3O2 NPs is obtained at 210oC and 10 hours. The result not only introduces a promising catalyst support Ti0.7Ir0.3O2 for much needed fuel cells, but it also open a new material type of Ir doped TiO2.
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Synthesis the new nanostructure Ti0.7W0.3O2 via low temperature solvothermal process / Tai Thien Huynh, Hau Quoc Pham, At Van Nguyen, Long Giang Bach, Son Truong Nguyen, Van Thi Thanh Ho // Applied Mechanics and Materials. - . - Vol. 876 (2018), P.84-90. - ISSN:

Switzerland : Trans Tech Publications, 2018
7 p.
Ký hiệu phân loại (DDC): 542
The materials currently used in proton-exchange membrane fuel cells (PEMFCs) require complex control of operating conditions to make them sufficiently durable to permit commercial deployment. One of the major materials challenges to allow simplification of fuel cell operating strategies is the discovery of catalyst supports that are much more stable to oxidative decomposition than currently used carbon blacks. Here, we report the synthesis and characterization of advanced nanostructure Ti0.7W0.3O2 prepared via a low-temperature solvothermal process without using any surfactants or stabilizers. A promising doped metal oxide is a candidate for such a durable catalyst support. The synthesized nanoparticles were characterized by XRD, TEM measurements. Results show that Ti0.7W0.3O2 exists in a single-phase solid solution with anatase phase of TiO2. Interestingly, the average particles size approximately 5 nm that could be promised to have a large specific surface area, which is an extremely important factor for promising catalyst support. Moreover, Ti0.7W0.3O2 synthesized at 200 oC for 6 hours obtains the smaller particles size without particles agglomeration compared to previous researches. These results open a new approach for synthesis nanostructure Ti0.7W0.3O2 by a solvothermal process for further application as catalyst support in PEMFCs.
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The comparison of surface modification methods of the heavy metals adsorption of activated carbon from rice husk / Hoa Thai Ma, Van Thi Thanh, Nguyen Bao Pham, Giang Long Bach, Tuan Dinh Phan // Applied Mechanics and Materials. - . - Vol. 876 (2018), P.91-96. - ISSN:

Switzerland : Trans Tech Publications, 2018
6 p.
Ký hiệu phân loại (DDC): 542
Surface modification of activated carbon (AC) could be done through different methods in order to modify their specific physical and chemical properties to facilitate metals removal from wastewater. Three methods were used to modify the rice husk AC (RHAC) including the use of (1) HNO3, (2) dithizone and (3) the combination of HNO3 with dithizone. These modification agents were increased its affinity towards the desired pollutant. The modification methods demonstrated the effective process for the metal ions adsorption capability and the removal of them from water. For Ni2+ and Cd2+ adsorption, RHAC was modified by HNO3 giving the best adsorption capacity in comparison with using dithizone or the combination of HNO3 with dithizone. That adsorption was reached 17.23 mg/g for Ni2+ and 29.61 mg/g for Cd2+. Additionally, the surface area, which was characterized by BET (Brunauer–Emmett–Teller) of RHAC, was 710.8 m2/g and DA micropore volume was 0.447 (cm3/g). Especially, the only modified RHACs had the peak of N-H functional group by using Fourier transform infrared spectrum (FTIR). Besides, the only RHAC modification by HNO3 had peak of C=O. That significantly contributed to increase the metal ions adsorption capacity of RHAC.
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